Mn Lalpha,beta and F Kalpha(1,2) (K-L(3,2)) X-ray fluorescence spectra of MnF(2) were measured when the excitation X-ray energy was higher and lower than the threshold energies. Monochromated synchrotron radiation was used for primary excitation. The resonance fluorescence of Mn Lbeta and the multiply ionized F Kalpha(3,4) satellites (KL-L(2)) were observed.