Methemoglobin formation during laser induced photothermolysis of vascular skin lesions

Lasers Surg Med. 2004;34(5):414-9. doi: 10.1002/lsm.20042.

Abstract

Background and objective: Monitoring dynamic changes during laser induced photothermolysis of vascular skin lesions is essential for obtaining an optimal therapeutic result. Rapid photoinduced thermal damage occurs at a threshold temperature of about 70 degrees C. It is therefore, relevant to identify markers to indicate if this threshold temperature has been reached. Methemoglobin, which is formed by a photo-induced oxidation of hemoglobin, indicates that the temperature has reached this threshold value. This study presents a proof of concept of a method for monitoring the in vivo presence of methemoglobin immediately after laser exposure.

Study design/materials and methods: The present study was designed to investigate the in vivo temperature dependence of hemoglobin absorption in the 450-800 nm spectrum range. In vivo diffuse reflectance measurements of port-wine stain (PWS) and telangiectasia were performed prior to, and immediately after, laser treatment with a pulsed dye laser (PDL) at 585 nm wavelength.

Results: In vivo measurements following laser treatment of vascular skin lesions showed an immediate increase in the optical absorption of blood. This effect, caused by thermal stress, is a result of an increased dermal blood volume fraction and methemoglobin formation. The effect is light dose dependent, and reflectance spectra revealed methemoglobin formation in patients treated with fluences above 5 J/cm2 at 585 nm wavelength.

Conclusions: It was proved that methemoglobin can be measured in vivo by reflectance spectroscopy. Measurements of the average methemoglobin concentrations immediately after laser exposure may be a valuable diagnostic tool to verify that the blood temperature has been sufficiently high to induce thermal damage to the vessel wall.

Publication types

  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Adolescent
  • Adult
  • Aged
  • Blood Volume
  • Child
  • Humans
  • Low-Level Light Therapy*
  • Melanins / metabolism
  • Methemoglobin / biosynthesis*
  • Middle Aged
  • Port-Wine Stain / metabolism
  • Port-Wine Stain / radiotherapy*
  • Skin / blood supply
  • Skin / metabolism*
  • Spectrum Analysis
  • Telangiectasis / metabolism
  • Telangiectasis / radiotherapy*

Substances

  • Melanins
  • Methemoglobin