Abstract
[reaction: see text] Exposure of monocarbonyl iodonium ylides, generated by the ester exchange of (Z)-(2-acetoxyvinyl)-lambda(3)-iodanes with EtOLi, to organoboranes results in a 1,2-shift of a carbon ligand from boron to the ylide carbons, which probably generates hitherto uncharacterized alpha-boryl ketones.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Boranes / chemistry*
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Hydrocarbons, Iodinated / chemical synthesis
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Hydrocarbons, Iodinated / chemistry*
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Molecular Structure
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Onium Compounds / chemical synthesis*
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Onium Compounds / chemistry*
Substances
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Boranes
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Hydrocarbons, Iodinated
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Onium Compounds