Rhodium-catalyzed carbonylative [2+2+1] cycloaddition reactions: catalytic formation of bicyclic cyclohexenones [corrected]

Sang Ick Lee; Ji Hoon Park; Young Keun Chung; Sueg-Geun Lee

doi:10.1021/ja039301+

Rhodium-catalyzed carbonylative [2+2+1] cycloaddition reactions: catalytic formation of bicyclic cyclohexenones [corrected]

J Am Chem Soc. 2004 Mar 10;126(9):2714-5. doi: 10.1021/ja039301+.

Authors

Sang Ick Lee¹, Ji Hoon Park, Young Keun Chung, Sueg-Geun Lee

Affiliation

¹ School of Chemistry and Center for Molecular Catalysis, Seoul National University, Seoul 151-747, Korea.

PMID: 14995184
DOI: 10.1021/ja039301+

Abstract

The rhodium-catalyzed carbonylative [3+2+1] cycloaddition of trienes into bicyclohexenones has been developed. The carbonylated cycloaddition products have a high regioselectivity. This catalytic system tolerates functionalities including ether, sulfonamide, and ester.

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