Initial surface roughening in Ge/Si(001) heteroepitaxy driven by step-vacancy line interaction

Phys Rev Lett. 2003 Oct 24;91(17):176102. doi: 10.1103/PhysRevLett.91.176102. Epub 2003 Oct 23.

Abstract

The initial surface roughening during Ge epitaxy on Si(001) is shown to arise from an effective repulsion between S(A) surface steps and dimer vacancy lines (VLs). This step-VL interaction gradually inactivates a substantial fraction of adatom attachment sites at the growth front, causing a rapid increase in the rate of two-dimensional island nucleation. The mutual repulsion hinders the crossing of S(A) surface steps over VLs in the second layer, thus organizing the developing surface roughness into a periodic array of anisotropic 2D terraces. Isolated (105) facets forming at specific sites on this ordered template mediate the assembly of first 3D Ge islands.