Cyanohydrin glycosides with unusual sugar residues: revised structure of passitrifasciatin

E S Olafsdottir; J W Jaroszewski; D S Seigler

doi:10.1016/0031-9422(91)85268-5

Cyanohydrin glycosides with unusual sugar residues: revised structure of passitrifasciatin

Phytochemistry. 1991;30(3):867-9. doi: 10.1016/0031-9422(91)85268-5.

Authors

E S Olafsdottir¹, J W Jaroszewski, D S Seigler

Affiliation

¹ Department of Organic Chemistry, Royal Danish School of Pharmacy, Copenhagen, Denmark.

PMID: 1367587
DOI: 10.1016/0031-9422(91)85268-5

Abstract

The cyclopentanoid cyanohydrin glycoside passitrifasciatin was reisolated, and shown to be (1S,4R)-1-(beta-D-gluopyranosyloxy)-4-(6-deoxy-beta-D-allopyran osyloxy)-2-cyclopentene-1-carbonitrile, using one- and two dimensional NMR spectroscopy, selective acid-catalysed cleavage of the glycosidic linkage of 6-deoxy-D-allose, and optical rotation data.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Carbohydrate Sequence
Glycosides / chemistry*
Glycosides / isolation & purification
Magnetic Resonance Spectroscopy
Molecular Sequence Data
Molecular Structure
Plants / chemistry

Substances

Glycosides
passitrifasciatin