Simultaneous determination of ticarcillin and clavulanate in rabbit serum and tissue cage fluid by liquid chromatography

J Chromatogr B Analyt Technol Biomed Life Sci. 2003 Sep 5;794(2):227-36. doi: 10.1016/s1570-0232(03)00456-2.

Abstract

A gradient elution HPLC method with a wavelength switch technique was developed to simultaneously analyze the beta-lactam ticarcillin and the beta-lactamase inhibitor clavulanate in rabbit serum and tissue cage fluid (TCF). A C18 reversed-phase column with a programmable UV detector changing the wavelength from 218 to 254 nm at 9 min was used for chromatographic separation. The mobile phase consisted of acetonitrile, phosphate buffer and tetrabutylammonium hydrogen sulfate by following a gradient elution program at a flow-rate of 1 ml/min. Sample processing was carried out with liquid-liquid extraction. Good linearity, recoveries, precision and accuracy were obtained. The ranges of the standard curves were 1-100 microg/ml for ticarcillin, and 0.2-20 microg/ml for clavulanate. This assay has been successfully applied to analyze ticarcillin and clavulanate in rabbit serum and tissue cage fluid samples from a pharmacokinetic study.

MeSH terms

  • Animals
  • Anti-Bacterial Agents / blood
  • Anti-Bacterial Agents / metabolism*
  • Anti-Bacterial Agents / pharmacokinetics
  • Clavulanic Acid / blood
  • Clavulanic Acid / metabolism*
  • Clavulanic Acid / pharmacokinetics
  • Rabbits
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Spectrophotometry, Ultraviolet
  • Ticarcillin / blood
  • Ticarcillin / metabolism*
  • Ticarcillin / pharmacokinetics
  • Tissue Distribution

Substances

  • Anti-Bacterial Agents
  • Clavulanic Acid
  • Ticarcillin