Electron-phonon scattering in metal clusters

Phys Rev Lett. 2003 May 2;90(17):177401. doi: 10.1103/PhysRevLett.90.177401. Epub 2003 Apr 29.

Abstract

Electron-lattice energy exchanges are investigated in gold and silver nanoparticles with sizes ranging from 30 to 2.2 nm embedded in different environments. Femtosecond pump-probe experiments performed in the low-perturbation regime demonstrate a strong increase of the intrinsic electron-phonon interaction for nanoparticles smaller than 10 nm due to a confinement effect.