A vanadium(IV) phosphite with a pillared layered structure: hydrothermal synthesis and characterization of (VO)4(4,4'-bpy)2(HPO3)4

Zhan Shi; Guanghua Li; Dong Zhang; Jia Hua; Shouhua Feng

doi:10.1021/ic0261676

A vanadium(IV) phosphite with a pillared layered structure: hydrothermal synthesis and characterization of (VO)4(4,4'-bpy)2(HPO3)4

Inorg Chem. 2003 Apr 7;42(7):2357-61. doi: 10.1021/ic0261676.

Authors

Zhan Shi¹, Guanghua Li, Dong Zhang, Jia Hua, Shouhua Feng

Affiliation

¹ State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China.

PMID: 12665370
DOI: 10.1021/ic0261676

Abstract

A novel vanadium(IV) phosphite, (VO)(4)(4,4'-bpy)(2)(HPO(3))(4), was hydrothermally synthesized and characterized by single-crystal X-ray diffraction. This compound crystallizes in the monoclinic system with the space group C2/c and cell parameters a = 35.970(3) A, b = 15.9400(13) A, c = 10.7681(7) A, beta = 101.073(4) degrees, and Z = 8 with R(1) = 0.0482. The structure of the compound consists of trigonal bipyramidal [VO(4)N] and pseudopyramidal [HPO(3)] blocks, which are connected by corner-sharing, to form vanadium phosphite layers in the bc plane. These layers are further linked through 4,4'-bpy pillars, generating a 3D framework. Thermogravimetric analysis and magnetic susceptibility data for this compound are given.