Determination of moniliformin in maize by ion chromatography

Anal Bioanal Chem. 2002 Nov;374(6):1086-90. doi: 10.1007/s00216-002-1565-7. Epub 2002 Oct 23.

Abstract

An ion chromatographic method for the determination of the mycotoxin moniliformin in maize was developed. The method contains a fast and simple clean-up procedure, which allows high volume sample injection. No further pre-concentration step is required. The limit of quantification was estimated to be 0.12 mg/kg moniliformin in maize. In contrast to the two previously published ion chromatographic methods, the moniliformin peak is base line separated and occurs in a region of a smooth base line in the ion chromatogram. The newly developed method showed a recovery through the whole analytical procedure of 97+/-3.5 %, whereas most previously described analytical methods had recoveries in the 70% range.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chromatography, High Pressure Liquid / methods*
  • Chromatography, Ion Exchange / methods*
  • Cyclobutanes / analysis*
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Zea mays / chemistry*

Substances

  • Cyclobutanes
  • moniliformin