A bis-bidentate dioxolene ligand induces thermal hysteresis in valence tautomerism interconversion processes

S H Bodnar; A Caneschi; A Dei; D A Shultz; L Sorace

doi:10.1039/b106192p

A bis-bidentate dioxolene ligand induces thermal hysteresis in valence tautomerism interconversion processes

Chem Commun (Camb). 2001 Oct 21:(20):2150-1. doi: 10.1039/b106192p.

Authors

S H Bodnar¹, A Caneschi, A Dei, D A Shultz, L Sorace

Affiliation

¹ Department of Chemistry, North Carolina State University, Raleigh, North Carolina, USA.

PMID: 12240207
DOI: 10.1039/b106192p

Abstract

The use of a bis-bidentate ligand in a solid cobalt dioxolene complex affords the necessary cooperative properties that lead to thermal hysteresis in a valence tautomeric interconversion equilibrium.