Bis(1,10-phenanthroline)(thiosulfato)manganese(II) methanol solvate and catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline)manganese(II)]-mu-thiosulfato]

Eleonora Freire; Sergio Baggio; Juan Carlos Muñoz; Ricardo Baggio

doi:10.1107/s0108270102012404

Bis(1,10-phenanthroline)(thiosulfato)manganese(II) methanol solvate and catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline)manganese(II)]-mu-thiosulfato]

Acta Crystallogr C. 2002 Aug;58(Pt 8):m455-8. doi: 10.1107/s0108270102012404. Epub 2002 Jul 31.

Authors

Eleonora Freire¹, Sergio Baggio, Juan Carlos Muñoz, Ricardo Baggio

Affiliation

¹ Universidad Nacional de la Patagonia, Sede Puerto Madryn, and CenPat, CONICET, 9120 Puerto Madryn, Chubut, Argentina.

PMID: 12154293
DOI: 10.1107/s0108270102012404

Abstract

The structure of bis(1,10-phenanthroline-kappa(2)N,N')(thiosulfato-kappa(2)O:S)manganese(II) methanol solvate, [Mn(S(2)O(3))(C(12)H(8)N(2))(2)].CH(3)OH, is made up of Mn(2+) centers coordinated to two bidentate phenanthroline (phen) groups and an S,O-chelating thiosulfate anion, forming monomeric entities. The structure of catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline-kappa(2)N,N')manganese(II)]-mu-thiosulfato-kappa(2)O:S], [Mn(S(2)O(3))(C(14)H(12)N(2))(H(2)O)(2)](n), is polymeric, consisting of Mn(dmph)(H(2)O)(2) units (dmph is 2,9-dimethyl-1,10-phenanthroline) linked by thiosulfate anions acting in an S,O-chelating manner.