A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions

Chem Commun (Camb). 2002 Jul 7:(13):1342-3. doi: 10.1039/b203301a.

Abstract

A novel coordination polymer of mixed-valence copper(I,II) with 4,4'-bipyridine and in situ oxidized isophthalate, [Cu2(ipO)(4,4'-bpy)] (ipOH = 2-hydroxyisophthalate), was hydrothermally synthesized and crystallographically characterized to be a laminated structure via weak copper(II)--oxygen interactions.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • 2,2'-Dipyridyl / chemistry
  • Copper / chemistry
  • Copper / metabolism*
  • Crystallography, X-Ray
  • Hot Temperature
  • Ligands
  • Magnetics
  • Models, Chemical
  • Molecular Structure
  • Oxidation-Reduction
  • Oxygen / metabolism*
  • Phthalic Acids / chemistry
  • Polymers / chemistry*

Substances

  • Ligands
  • Phthalic Acids
  • Polymers
  • isophthalate
  • 2,2'-Dipyridyl
  • Copper
  • Oxygen