Noninvasive imaging of peripherally injected Alzheimer's disease type synthetic A beta amyloid in vivo

Bioconjug Chem. 2002 Mar-Apr;13(2):276-84. doi: 10.1021/bc010066z.

Abstract

The pathological hallmark of Alzheimer's disease (AD) is accumulation in the brain of amyloid composed of the 40-mer peptide A beta. Many fundamental questions about the biology of (AD) remain unanswered because there is currently no method of quantifying A beta amyloid in vivo. A noninvasive method of detecting and quantifying A beta amyloid in vivo would have wide application for the premortem diagnosis of AD and the efficient evaluation of candidate therapeutics aimed at inhibiting the formation and growth of A beta amyloid. Taking advantage of the extraordinarily high affinity of A beta for itself, we have synthesized an N'-terminal diethylenetriaminepentaacetic acid (DTPA) derivative of A beta possessing the kinetic activity and specificity for A beta amyloid desired of a probe to be used for noninvasive imaging. DTPA-A beta(3-40) is readily labeled with (111)InOAc(3) to yield a stable probe with exquisite specificity for naturally occurring and synthetic A beta amyloid in vitro. Moreover, (111)In-DTPA-A beta(3-40), administered intravascularly can specifically deposit onto and label previously injected synthetic A beta amyloid and be imaged in vivo with a gamma camera. The present results demonstrate the design, synthesis, and use of an A beta amyloid-specific probe and methods for its use as a noninvasive imaging agent. In vivo imaging of A beta amyloid represents an important step toward the development of biochemically based objective tools for the assessment of progression of AD and efficacy of potential therapeutics.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Alzheimer Disease / metabolism*
  • Amino Acid Sequence
  • Amyloid beta-Peptides / administration & dosage
  • Amyloid beta-Peptides / blood
  • Amyloid beta-Peptides / chemical synthesis*
  • Amyloid beta-Peptides / pharmacokinetics*
  • Animals
  • Brain / metabolism
  • Half-Life
  • Humans
  • Indium Radioisotopes
  • Molecular Sequence Data
  • Muscle, Skeletal / metabolism
  • Pentetic Acid / chemistry
  • Rats
  • Rats, Sprague-Dawley
  • Staining and Labeling

Substances

  • Amyloid beta-Peptides
  • Indium Radioisotopes
  • Pentetic Acid