Amlodipine bioequivalence study: quantification by liquid chromatography coupled to tandem mass spectrometry

Biopharm Drug Dispos. 2001 Dec;22(9):383-90. doi: 10.1002/bdd.282.

Abstract

Objective: To assess the bioequivalence of two amlodipine tablet formulations (Amlodipine 5 mg tablet from Merck S.A. Indústrias Químicas, Brazil as test formulation and Norvasc 5 mg tablet from Laboratórios Pfizer Ltd., Brazil as reference formulation) in 24 healthy volunteers of both sexes.

Methods: The study was conducted using an open, randomized two-period crossover design with a 4-week washout interval. Plasma samples were obtained over a 144 h period. Plasma amlodipine concentrations were analyzed by combined liquid chromatography coupled to tandem mass spectrometry (LC-MS-MS) with positive ion electrospray ionization using multiple reaction monitoring (MRM). From the amlodipine plasma concentration vs time curves, the following pharmacokinetic parameters were obtained: AUC(last), AUC(0-inf) and C(max). The statistical interval proposed was 80-125% according to the US Food and Drug Administration Agency.

Results: The limit of quantification was 0.1 ng/ml for plasma amlodipine analysis. The geometric mean and the 90% confidence interval (CI) test/reference ratios were 101.2 (92.9-110.2%) for AUC(last), 99.6 (91.5-108.4%) for AUC(0-inf) and 98.5 (89.0-109.1%) for C(max).

Conclusion: Since the 90% CI for AUC(last), AUC(0-inf) and C(max) ratios were within in the 80-125% interval proposed by the US FDA, it was concluded that Amlodipine 5 mg tablet (test formulation) was bioequivalent to Norvasc 5 mg tablet, in terms of both rate and extent of absorption.

Publication types

  • Clinical Trial
  • Randomized Controlled Trial

MeSH terms

  • Adolescent
  • Adult
  • Amlodipine / blood
  • Amlodipine / chemistry
  • Amlodipine / pharmacokinetics*
  • Antihypertensive Agents / blood
  • Antihypertensive Agents / chemistry
  • Antihypertensive Agents / pharmacokinetics*
  • Chemistry, Pharmaceutical
  • Chromatography, High Pressure Liquid / methods
  • Confidence Intervals
  • Cross-Over Studies
  • Female
  • Humans
  • Linear Models
  • Male
  • Mass Spectrometry / methods
  • Tablets
  • Therapeutic Equivalency

Substances

  • Antihypertensive Agents
  • Tablets
  • Amlodipine