Mapping the one-dimensional electronic States of nanotube peapod structures

Science. 2002 Feb 1;295(5556):828-31. doi: 10.1126/science.1068133. Epub 2002 Jan 3.

Abstract

Arrays of C60 molecules nested inside single-walled nanotubes represent a class of nanoscale materials having tunable properties. We report electronic measurements of this system made with a scanning tunneling microscope and demonstrate that the encapsulated C60 molecules modify the local electronic structure of the nanotube. Our measurements and calculations also show that a periodic array of C60 molecules gives rise to a hybrid electronic band, which derives its character from both the nanotube states and the C60 molecular orbitals.