Bis(2,2':6',2"-terpyridine-kappa3N)manganese(II) tetrathionate trihydrate

E Freire; S Baggio; M T Garland; R Baggio

doi:10.1107/s0108270101016481

Bis(2,2':6',2"-terpyridine-kappa3N)manganese(II) tetrathionate trihydrate

Acta Crystallogr C. 2001 Dec;57(Pt 12):1403-4. doi: 10.1107/s0108270101016481. Epub 2001 Dec 6.

Authors

E Freire¹, S Baggio, M T Garland, R Baggio

Affiliation

¹ Universidad Nacional de la Patagonia, Sede Puerto Madryn, and CenPat, CONICET, Puerto Madryn, Chubut, Argentina.

PMID: 11740097
DOI: 10.1107/s0108270101016481

Abstract

The structure of the title compound, [Mn(tpy)2](S4O6)*3H2O (tpy is 2,2':6',2"-terpyridine, C15H11N3), consists of monomeric [Mn(tpy)2]2+ units embedded in a complex anionic network made up of tetrathionate ions and hydration water molecules connected via a complex hydrogen-bonding scheme.