Ubiquitination of a novel deubiquitinating enzyme requires direct binding to von Hippel-Lindau tumor suppressor protein

J Biol Chem. 2002 Feb 15;277(7):4656-62. doi: 10.1074/jbc.M108269200. Epub 2001 Dec 5.

Abstract

von Hippel-Lindau (VHL) disease is a hereditary cancer syndrome caused by germline mutations of the VHL gene. Recent studies suggest that VHL protein (pVHL) is a component of an E3 ubiquitin ligase, but the detailed biological function of pVHL remains to be determined. To further elucidate the biological functions of pVHL, we searched pVHL-interacting proteins using yeast two-hybrid screening. A novel protein named VHL-interacting deubiquitinating enzyme 1 (VDU1) was identified as being able to directly interact with pVHL in vitro and in vivo. We have determined the full-length cDNA of this enzyme, which includes two putative subtypes. Type I consists of 942 amino acids, and type II consists of 911 amino acids with predicted molecular masses of 107 and 103 kDa, respectively. We have also cloned a mouse homologue of this enzyme. Sequence analysis reveals that this protein is conserved between human and mouse and contains the signature motifs of the ubiquitin-specific processing protease family. Enzymatic function studies demonstrate its deubiquitinating activity. We have determined that the VDU1-interacting region in pVHL is located in its beta-domain, and several naturally occurring mutations located in this domain disrupt the interaction between pVHL and VDU1 protein. Co-immunoprecipitation demonstrates that VDU1 can be recruited into the pVHL-elongin C-elongin B complex. Finally, we demonstrate that VDU1 is able to be ubiquitinated via a pVHL-dependent pathway for proteasomal degradation, and VHL mutations that disrupt the interaction between VDU1 and pVHL abrogate the ubiquitination of VDU1. Our findings indicate that VDU1, a novel ubiquitin-specific processing protease, is a downstream target for ubiquitination and degradation by pVHL E3 ligase. Targeted degradation of VDU1 by pVHL could be crucial for regulating the ubiquitin-proteasome degradation pathway.

MeSH terms

  • Amino Acid Sequence
  • Amino Acids / chemistry
  • Animals
  • Binding Sites
  • Blotting, Northern
  • Blotting, Western
  • COS Cells
  • DNA, Complementary / metabolism
  • Electrophoresis, Polyacrylamide Gel
  • Endopeptidases / biosynthesis*
  • Endopeptidases / chemistry*
  • Glutathione Transferase / metabolism
  • Humans
  • Immunoblotting
  • Ligases / chemistry
  • Ligases / metabolism*
  • Mice
  • Molecular Sequence Data
  • Mutation
  • Plasmids / metabolism
  • Polymerase Chain Reaction
  • Precipitin Tests
  • Protein Binding
  • Protein Structure, Tertiary
  • RNA, Messenger / metabolism
  • Sequence Analysis, DNA
  • Sequence Homology, Amino Acid
  • Transfection
  • Tumor Cells, Cultured
  • Tumor Suppressor Proteins*
  • Two-Hybrid System Techniques
  • Ubiquitin / metabolism*
  • Ubiquitin Thiolesterase
  • Ubiquitin-Protein Ligases
  • Von Hippel-Lindau Tumor Suppressor Protein

Substances

  • Amino Acids
  • DNA, Complementary
  • RNA, Messenger
  • Tumor Suppressor Proteins
  • Ubiquitin
  • Ubiquitin-Protein Ligases
  • Von Hippel-Lindau Tumor Suppressor Protein
  • Glutathione Transferase
  • Endopeptidases
  • USP33 protein, human
  • Ubiquitin Thiolesterase
  • Ligases
  • VHL protein, human