catena-Poly[[diaqua(1,10-phenanthrolone-N,N')manganese(II)]-mu-(thiosulfato-O:S] and bis(2,2'-bi-pyridyl-N,N')(tetrathionato-O,O')-manganese(II)

E Freire; S Baggio; R Baggio; A Mombrú

doi:10.1107/s0108270100013585

catena-Poly[[diaqua(1,10-phenanthrolone-N,N')manganese(II)]-mu-(thiosulfato-O:S] and bis(2,2'-bi-pyridyl-N,N')(tetrathionato-O,O')-manganese(II)

Acta Crystallogr C. 2001 Jan;57(Pt 1):14-7. doi: 10.1107/s0108270100013585.

Authors

E Freire¹, S Baggio, R Baggio, A Mombrú

Affiliation

¹ Universidad Nacional de la Patagonia, Sede Puerto Madryn and CenPat, CONICET, 9120 Puerto Madryn, Chubut, Argentina.

PMID: 11173381
DOI: 10.1107/s0108270100013585

Abstract

The structures of [Mn(S2O3)2(C12H8N2)(H2O(2)] and [Mn(S4O6)(C10H8N2)(2)] are presented. The former consists of pairs of polymeric chains formed by manganese polyhedra bridged by bidentate thiosulfate anions, which are in turn related to each other by a pseudo-twofold screw axis. The latter has crystallographic twofold symmetry and consists of monomers in which manganese displays its typical octahedral coordination provided by the bidentate bites of two bipyridine bases and a tetrathionate anion, which is, to our knowledge, the first chelating tetrathionate to be reported in the literature.