Membrane thinning effect of the beta-sheet antimicrobial protegrin

Biochemistry. 2000 Jan 11;39(1):139-45. doi: 10.1021/bi991892m.

Abstract

Lipid bilayers containing the antimicrobial peptide protegrin-1 (PG-1) were studied by lamellar X-ray diffraction. Previously, we have shown that the peptide exists in two distinct states when associated with lipid bilayers depending on the peptide concentration [Heller, W. T., Waring, A. J., Lehrer, R. I., and Huang, H. W. (1998) Biochemistry 37, 17331-17338]. For concentrations below a lipid-dependent threshold, PG-1 exhibits a unique oriented circular dichroism spectrum called the S state. X-ray experiments show that in this state PG-1 decreases the thickness of the lipid bilayer in proportion to the peptide concentration, similar to alamethicin's membrane thinning effect. This indicates that the S state is adsorbed in the headgroup region of the lipid bilayer, where the peptide is in an inactive state. For PG-1 above the threshold concentration, X-ray diffraction shows that the interaction between the peptide and the bilayer changes significantly. These results suggest that PG-1 has the same concentration-gated mechanism of action as alamethicin.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Alamethicin / chemistry
  • Amino Acid Sequence
  • Anti-Infective Agents / chemistry*
  • Antimicrobial Cationic Peptides
  • Lipid Bilayers / chemistry*
  • Molecular Sequence Data
  • Peptides / chemistry
  • Phosphatidylcholines / chemistry
  • Protein Structure, Secondary
  • Proteins / chemistry*
  • X-Ray Diffraction

Substances

  • Anti-Infective Agents
  • Antimicrobial Cationic Peptides
  • Lipid Bilayers
  • Peptides
  • Phosphatidylcholines
  • Proteins
  • protegrin-1
  • Alamethicin
  • 1,2-diphytanoylphosphatidylcholine