Ion chromatographic determination of bromate in drinking water by post-column reaction with fuchsin

J Chromatogr A. 1999 Jun 25;847(1-2):271-7. doi: 10.1016/s0021-9673(99)00190-9.

Abstract

Bromate deriving from ozonation treatment of bromide containing waters are analyzed by ion-exchange chromatography with spectrophotometric detection after post-column reaction with fuchsin in low pH medium. An anion-exchange column was used with 2.7 mM carbonate-0.3 mM hydrogencarbonate eluent. The eluent from the column was then allowed to react with a SO2-reduced fuchsin solution and then with a diluted HCl solution at 65 degrees C. The developed colour of the final product was measured spectrophotometrically at 530 nm. Linearity was checked up to 50 micrograms/l with a 200-microliter injection loop (r2 = 0.9997) and up to 100 micrograms/l of bromate with 100 microliters loop (r2 = 0.9939). Nitrate, sulfate, bromide, phosphate, fluoride did not interfere at 100 mg/l concentration level; only nitrite at concentration levels greater than 3 mg/l caused partial overlapping with bromate peak, but this value is not likely to occur in common drinking water. The detection limit (3 sigma) is 0.1 microgram/l (1 microgram/l propagation error approach).

MeSH terms

  • Bromates / analysis*
  • Calibration
  • Chromatography, Liquid / methods*
  • Rosaniline Dyes / chemistry*
  • Sensitivity and Specificity
  • Water Supply / analysis*

Substances

  • Bromates
  • Rosaniline Dyes