Bovine lens crystallins do contain helical structure: a circular dichroism study

Biochim Biophys Acta. 1999 Jul 13;1432(2):234-8. doi: 10.1016/s0167-4838(99)00107-7.

Abstract

In order to settle a recent discussion on the secondary structure of lens crystallins, we have measured the circular dichroism (CD) spectra of alpha-, beta(H)-, and beta(L)-crystallin from 178 to 250 nm and of gamma-crystallin from 168 to 250 nm. The results were analysed by means of a newly developed algorithm that almost doubles the reliability of secondary structure prediction and that allows discrimination between alpha- and 3(10)-helical, and between extended and polyproline beta-type structure. The results indicate that the crystallins studied contain a non-negligible amount of alpha-helical structure, although at least 50% of it is in the form of single and/or distorted loops. In alpha-crystallin, which is related to the chaperones, the helical content is lower than in beta- and gamma-crystallin. In some cases, the helices may play a role in DNA binding by the crystallins.

Publication types

  • Comparative Study

MeSH terms

  • Animals
  • Cattle
  • Circular Dichroism
  • Crystallins / chemistry*
  • Crystallins / genetics
  • Protein Structure, Secondary
  • Software

Substances

  • Crystallins